問題詳情

複選題
32. For the reaction show below, which of the following statements are correct? Ni0L4+ CO⇌Ni0L3CO + L
(A) The forward reaction is likely to go by the Dissociative ( D ) mechanism.
(B) The forward reaction should possess a large positive

and a large negative

.
(C) To obtain the △G for the reaction, you can measure rates of forward reaction at different temperatures to
determine rate constants, and plot In k vs. I/T.
(D) PPh3 would yield the largest value of Keq and △G for the reaction as compared to PMe3 and P(OEt)3. This
statement should be attributed to the electronic argument.
(E) The presence of higher concentration of CO should shift the equilibrium to the right.

參考答案